By Phyllis R. Brown
"Volume forty provides an authoritative collection of the simplest and latest study findings in separation technological know-how. Surveys contemporary advancements in excessive performance-liquid (HPLC), reversed-phase liquid (RPLC), countercurrent (CCC), and micellar electrokinetic chromatography (MEKC)."
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Extra resources for Advances in Chromatography, Volume 40
Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, Budapest, Hungary R. D. Department of Chemistry, University "La Sapienza," Rome, Italy Page iv G. D. Department of Chemistry, University "La Sapienza," Rome, Italy Joe M. D. Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, Illinois Dieter L. D. D. Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, Budapest, Hungary A. D. D. Department of Chemistry, University of Tennessee, Knoxville, and Division of Chemical and Analytical Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee Ajith D.
Life Science Group, Bio-Rad Laboratories, Hercules, California Lars-Erik Magnusson Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, Illinois Page v S. D. D. * Department of Chemistry, University of Tennessee, Knoxville, and Division of Chemical and Analytical Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee D. D. Department of Chemistry, University "La Sapienza," Rome, Italy Colin F. Sc. Department of Chemistry, Wayne State University, Detroit, Michigan Salwa K.
The difference between DGliq and DGgas represents a solvent effect (DGsolv) on the change of Gibbs free energy associated with the liquid-phase adsorption: where DA is the reduction of hydrophobic surface area due to the adsorption of the solute onto the ODS ligand. By combining Eqs. (6) and (8), the equilibrium constant, K, of a solute in a mobile phase i in equilibrium with the RPLC adsorbent (Ki) can be expressed as follows [29,30]: The contribution of the electrostatic term [the third term on the right-hand side (RHS) of Eq.
Advances in Chromatography, Volume 40 by Phyllis R. Brown